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Record-high hyperpolarizabilities in atomically precise single metal-doped silver nanoclusters

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Nanoscale Horiz., 2025, 10,314-321
DOI: 10.1039/D4NH00454J, Communication
Hao Yuan, Isabelle Russier-Antoine, Christophe Moulin, Pierre-François Brevet, Željka Sanader Maršić, Martina Perić Bakulić, Xi Kang, Rodolphe Antoine, Manzhou Zhu
Second-order nonlinear optical scattering properties of Ag25 nanoclusters are strongly affected by the nature of the metal dopant. Also, hyperpolarizabilities are one order higher than the one reported for Au25 nanoclusters and represent the largest values ever reported for nanoclusters.
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