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Mechanism of photocatalytic CO2 methanation on ultrafine Rh nanoparticles

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Nanoscale Horiz., 2024, 9,627-636
DOI: 10.1039/D3NH00506B, Communication
Xinyan Dai, Yugang Sun
The photoexcited hot electrons in rhodium (Rh) nanoparticles supported on silica spheres promote the cleavage of both C–O bonds in CO2 molecules with the assistance of hydrogen, favoring the selectivity and kinetics of CO2 methanation.
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