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Role of carboxylates in the phase determination of metal sulfide nanoparticles

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Nanoscale Horiz., 2023, 8,1386-1394
DOI: 10.1039/D3NH00227F, Communication
Open Access Open Access
Creative Commons Licence&nbsp This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
Andrey A. Shults, Guanyu Lu, Joshua D. Caldwell, Janet E. Macdonald
At low carboxylate concentrations the sulfur source is highly reactive thiourea, which gives rise to sulfur rich nanoparticles. At high carboxylate concentrations, the sulfur source is the less reactive thiocyanate, resulting in sulfur poor phases.
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