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Supramolecular nanocapsules as two-fold stabilizers of outer-cavity sub-nanometric Ru NPs and inner-cavity ultra-small Ru clusters

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Nanoscale Horiz., 2022, 7,607-615
DOI: 10.1039/D1NH00677K, Communication
Ernest Ubasart, Irene Mustieles Marin, Juan Manuel Asensio, Gabriel Mencia, Ángela M. López-Vinasco, Cristina García-Simón, Iker del Rosal, Romuald Poteau, Bruno Chaudret, Xavi Ribas
The synthesis of metallic nanoparticles with high surface area and known shape is of paramount importance to increase their catalytic properties. Here we show how a nanocapsule is able to control the formation of [Ru5] clusters and sub-nanometric Ru NPs.
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