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Covalent modification of franckeite with maleimides: connecting molecules and van der Waals heterostructures

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Nanoscale Horiz., 2021, Advance Article
DOI: 10.1039/D1NH00147G, Communication
Julia Villalva, Sara Moreno-Da Silva, Palmira Villa, Luisa Ruiz-González, Cristina Navío, Saül Garcia-Orrit, Víctor Vega-Mayoral, Juan Cabanillas-González, Andrés Castellanos-Gomez, Emerson Giovanelli, Emilio M. Pérez
We show that thiol–ene-like “click” chemistry can be used to decorate franckeite, a naturally occurring van der Waals heterostructure with maleimide reagents. In this way, we provide a pathway towards 2D–2D–0D mixed-dimensional heterostructures.
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